Fashion’s Night Out officially kicked off last night with supermodels like Naomi Campbell and Gisele Bundchen taking to the runway at Lincoln Center in New York City. Gossip Girl’s Blake Lively however stole the show in a bold printed Marchesa dress. She showed off her toned arms and equally toned legs and accessorized with stacked bangles and a pair of black Christian Louboutin pumps with chunky heels. Gossip Girl returns to the CW Monday, September 13th 2010 at 9/8c.

Blake Lively looks incredibly chic in a bold dress at Fashion’s Night Out. (Photo by Larry Busacca/Getty Images for Conde Nast)

Blake Lively and Editor-in-Chief of Vogue, Anna Wintour get ready for the major runway show at Fashion’s Night Out NYC. (Photo by Larry Busacca/Getty Images for Conde Nast)